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Lithium Tetrafluoroborate (LiBF4) Electrolyte Salt

CAS Number: 14283-07-9

Lithium tetrafluoroborate (LiBF4) is an electrolyte salt valued for excellent low-temperature performance and stability in propylene carbonate-based systems, making it suitable for low-temperature and wide-voltage Li-ion applications. Its lower melting point versus LiPF6 facilitates dissolution in less polar solvents.

Technical Specifications

Fe (ppm)≤2
appearanceWhite crystalline powder
purity (%)≥99.5
moisture (ppm)≤30
free acid as HF (ppm)≤50

Applications

  • Low-temperature lithium-ion battery electrolytes (-40°C operation)
  • PC-based electrolyte formulations for lithium primary batteries
  • Capacitor electrolyte additive
  • Electroplating and surface finishing
  • Ionic liquid synthesis intermediate

Key Features

  • Superior low-temperature discharge retention compared to LiPF6 electrolytes
  • Compatible with PC solvent, preventing graphite exfoliation when used correctly
  • High purity reduces parasitic reactions and extends shelf life of formulated electrolytes
  • Packaged under inert atmosphere to maintain anhydrous quality during transport

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Lithium Tetrafluoroborate (LiBF4) Electrolyte Salt chemical structure

CAS Number

14283-07-9

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