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Polyethylene Glycol Diglycidyl Ether (PEGDGE)

CAS Number: 72207-80-8

Polyethylene Glycol Diglycidyl Ether (PEGDGE) is a difunctional flexible epoxy based on polyethylene glycol (PEG-200 or PEG-400) end-capped with glycidyl ether groups, providing a long flexible PEG spacer between the two reactive epoxide termini with EEW of 170–250 g/eq. Used as a reactive flexibilizer and diluent, it reduces brittleness and increases peel strength in rigid epoxy systems, adds hydrophilicity, and improves cryogenic-temperature performance. It is also used as the crosslinker in biomedical hydrogels and water-swellable sealants where biocompatibility and chain flexibility are required.

Technical Specifications

EEW170–250 g/eq
viscosity30–100 mPa·s at 25 °C
appearanceClear, colorless to pale yellow liquid
PEGBackbonePEG-200 or PEG-400
miscibilityFully miscible with water and most epoxy resins

Applications

  • Reactive flexibilizer and diluent in rigid epoxy systems
  • Peel-strength improvement in structural epoxy adhesives
  • Biomedical and pharmaceutical hydrogel crosslinker
  • Water-swellable sealant and gasket formulations
  • Cryogenic adhesives and coatings for LNG equipment

Key Features

  • PEGDGE acts as a reactive flexibilizer — incorporates into the cured network without migration, permanently improving toughness
  • Long PEG spacer dramatically reduces glass transition temperature and improves cryogenic flexibility
  • Water miscibility makes PEGDGE a unique hydrophilic epoxy component for waterborne and hydrogel applications
  • Low viscosity (<100 mPa·s) reduces overall system viscosity without sacrificing cure chemistry

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Polyethylene Glycol Diglycidyl Ether (PEGDGE) chemical structure

CAS Number

72207-80-8

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