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3-O-Ethyl Ascorbic Acid (EAA)

CAS Number: 86404-04-8

3-O-Ethyl Ascorbic Acid (EAA) is an ether derivative of ascorbic acid where the hydroxyl group at the C-3 position is protected by an ethyl group, delivering superior chemical stability in both aqueous and oil phases compared to L-ascorbic acid. It penetrates the stratum corneum effectively and is cleaved intracellularly to release free ascorbic acid, providing potent tyrosinase inhibition approximately twice that of kojic acid. Used at 0.5–3% in brightening formulations, it remains color-stable throughout the product's shelf life.

Technical Specifications

purity≥98.0% (HPLC)
storageSealed container, cool and dry; stable 2 years at room temperature
appearanceWhite to off-white crystalline powder
heavy metals<10 ppm
loss on drying≤1.0%
pH (2% aqueous)4.5–6.5
recommended dosage0.5–3.0%

Applications

  • High-performance vitamin C brightening serums
  • Stable whitening ampoules and concentrates
  • Day creams with combined antioxidant and UV defense
  • Combination formulas with tranexamic acid or niacinamide
  • Anti-aging creams targeting uneven skin tone and fine lines

Key Features

  • 3-O-Ethyl Ascorbic Acid (EAA) provides tyrosinase inhibition approximately 2× stronger than kojic acid
  • Stable in both water and oil phases — no yellowing, formulation-friendly across pH and temperature ranges
  • Effectively penetrates stratum corneum and converts to free ascorbic acid intracellularly
  • Compatible with niacinamide, peptides, and AHA/BHA actives without the instability issues of L-ascorbic acid

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3-O-Ethyl Ascorbic Acid (EAA) chemical structure

CAS Number

86404-04-8

Availability

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