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Lithium Bis(trifluoromethanesulfonyl)imide (LiTFSI)

CAS Number: 90076-65-6

LiTFSI is a thermally and chemically stable lithium salt widely used in solid-state electrolytes, gel polymer batteries, and lithium-sulfur systems. Its large, delocalized anion provides excellent ionic conductivity across a wide temperature range and superior resistance to moisture-induced degradation.

Technical Specifications

Cl (ppm)≤30
Fe (ppm)≤1
appearanceWhite crystalline powder
purity (%)≥99.9
moisture (ppm)≤50
free acid (ppm)≤80

Applications

  • Solid-state polymer electrolyte (PEO-based) systems
  • Lithium-sulfur battery electrolyte
  • Gel polymer electrolyte formulation
  • Ionic liquid-based electrolytes
  • Supercapacitor and hybrid energy storage electrolytes

Key Features

  • Outstanding thermal stability up to 360°C enables high-temperature battery applications
  • Highly soluble in polar aprotic solvents and PEO matrices
  • Large TFSI anion promotes lithium-ion dissociation and high conductivity
  • Non-corrosive to stainless steel at concentrations used in solid-state systems

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Lithium Bis(trifluoromethanesulfonyl)imide (LiTFSI) chemical structure

CAS Number

90076-65-6

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