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Ammonium Polyphosphate (APP) Phase I

CAS Number: 68333-79-9

Ammonium polyphosphate Phase I (APP I) is a lower-polymerization-degree, water-soluble intumescent flame retardant suited for textile backcoating, paper treatment, and aqueous formulations. With a polymerization degree of approximately 10–100, it dissolves readily in water, enabling straightforward incorporation into waterborne systems. APP I releases phosphoric acid and ammonia upon heating, creating an efficient char-forming mechanism for cellulosic substrates.

Technical Specifications

appearanceWhite crystalline powder
pH (10% solution)5.5–7.0
nitrogen content (%)13–15
phosphorus content (%)30–31
degree of polymerization10–100
water solubility (25°C, g/100mL)5–10

Applications

  • Waterborne flame-retardant textile backcoatings and finishes
  • Fire-retardant paper and cardboard impregnation
  • Aqueous intumescent coatings for wood and cellulosic substrates
  • Agricultural fertilizer–flame retardant dual-function formulations
  • Flame-retardant adhesives and binders in construction materials

Key Features

  • Water-soluble grade enables seamless integration into aqueous and waterborne formulations
  • Effective acid source and foaming agent in cellulosic and textile FR systems
  • Good compatibility with urea, dicyandiamide, and other nitrogen co-synergists
  • Cost-effective flame retardancy for non-durable or semi-durable textile applications

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Ammonium Polyphosphate (APP) Phase I chemical structure

CAS Number

68333-79-9

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