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Antimony Trioxide (Sb2O3) Flame Retardant Synergist

CAS Number: 1309-64-4

Antimony trioxide (Sb2O3) is the dominant inorganic synergist used in combination with halogenated flame retardants to dramatically enhance their effectiveness. In the gas phase, it reacts with HBr/HCl from decomposing halogen FRs to form antimony halides and oxyhalides that are highly effective radical chain scavengers. A typical 3:1 (halogen FR : Sb2O3) loading synergistically achieves UL94 V-0 ratings that neither component could reach alone. Sb2O3 is essential in PVC, HIPS, ABS, polyester, and rubber compounds using brominated or chlorinated FRs.

Technical Specifications

appearanceWhite fine powder
moisture (%)<0.2
Sb2O3 content (%)≥99.5
heavy metals (ppm)<50
oil absorption (g/100g)10–25
particle size D50 (µm)0.3–1.5 (multiple grades)

Applications

  • Synergist with brominated FRs (TBBPA, deca-BDE, BER) in HIPS, ABS, and nylon compounds
  • PVC cable and wire insulation with chlorinated FR synergism
  • Polyester, PBT, and PET compounds using EBTBPI or brominated FR
  • Rubber and elastomer compounds using halogenated flame retardants
  • Textile back-coating systems with halogenated FR for furniture and drapery

Key Features

  • Multiplies effectiveness of halogen FRs: 3:1 (halogen:Sb2O3) synergism reduces total FR loading significantly
  • Available in ultra-fine grades (D50 < 0.5 µm) for minimal impact on surface gloss and optical properties
  • Surface-treated grades with stearic acid or silane available for improved dispersion in polymers
  • Widely approved in global FR standards and UL certifications for use with brominated and chlorinated systems

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Antimony Trioxide (Sb2O3) Flame Retardant Synergist chemical structure

CAS Number

1309-64-4

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