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Ammonium Polyphosphate (APP) Phase II

CAS Number: 68333-79-9

Ammonium polyphosphate Phase II (APP II) is a high-degree-of-polymerization, water-insoluble intumescent flame retardant widely used in coatings, adhesives, and polymer systems. With a polymerization degree exceeding 1000, it delivers superior humidity resistance and long-term durability compared to Phase I grades. APP II acts simultaneously as an acid source and blowing agent in intumescent systems, forming a protective char layer that suppresses flame spread.

Technical Specifications

appearanceWhite powder
nitrogen content (%)14–15
phosphorus content (%)31–32
degree of polymerization>1000
decomposition temperature (°C)>300
water solubility (25°C, g/100mL)<0.5

Applications

  • Intumescent fireproofing coatings for steel structures
  • Halogen-free flame retardant polypropylene and polyethylene compounds
  • Expandable fire-retardant adhesives and sealants
  • Wood and cellulosic substrate impregnation treatments
  • Rigid polyurethane foam with improved fire resistance

Key Features

  • High polymerization degree (>1000) ensures excellent water and humidity resistance
  • Dual function as acid source and blowing agent in intumescent systems reduces additive count
  • Halogen-free and low-smoke formulation meets REACH and RoHS compliance requirements
  • Fine particle size (D50 ≈ 15 µm) promotes uniform dispersion in coatings and polymers

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Ammonium Polyphosphate (APP) Phase II chemical structure

CAS Number

68333-79-9

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