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Pentaerythritol (PER) Flame Retardant Grade

CAS Number: 115-77-5

Pentaerythritol (PER) flame retardant grade is a high-purity polyol specifically used as the carbonific (carbon-forming) component of intumescent flame retardant systems for coatings, polyolefins, and thermoplastic composites. It reacts with the acid source (typically ammonium polyphosphate) upon decomposition to produce a cross-linked, thermally insulating char. High-purity FR grade PER with minimized mono-PE content is preferred for consistent char formation and coating film integrity in demanding fireproofing applications.

Technical Specifications

appearanceWhite crystalline powder
moisture (%)<0.1
ash content (%)<0.005
melting point (°C)258–260
di-pentaerythritol content (%)<1.5
mono-pentaerythritol content (%)≥98

Applications

  • Solvent-borne intumescent structural steel fireproofing coatings (30-year fire protection)
  • Waterborne intumescent wood and timber coatings for Class 1 surface spread of flame
  • Halogen-free intumescent FR polyolefin compounds for cables and automotive
  • Passive fire protection boards, batts, and blankets with charring binder
  • Intumescent pipe collars and cable transit fire stop systems

Key Features

  • High mono-PE purity (≥98%) ensures consistent char formation kinetics and coating film quality
  • Four hydroxyl groups per molecule deliver maximum theoretical char yield in IFR systems
  • Low ash content (<0.005%) prevents yellowing and discoloration of white intumescent coatings
  • Well-characterized reaction kinetics with APP enable precise formulation of intumescent systems

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Pentaerythritol (PER) Flame Retardant Grade chemical structure

CAS Number

115-77-5

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