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Melamine Polyphosphate (MPP)

CAS Number: 218768-84-4

Melamine polyphosphate (MPP) is a halogen-free, nitrogen–phosphorus synergistic flame retardant offering excellent thermal stability up to 320 °C, making it particularly suitable for high-processing-temperature engineering plastics. It functions by releasing non-combustible gases and promoting char formation simultaneously, providing both gas-phase and condensed-phase fire suppression. MPP is a preferred alternative to older melamine derivatives in glass-fiber-reinforced PA6 and PA66 systems.

Technical Specifications

appearanceWhite powder
moisture content (%)<0.3
nitrogen content (%)41–43
phosphorus content (%)13–14
particle size D50 (µm)5–15
thermal decomposition onset (°C)>320

Applications

  • Glass-fiber-reinforced polyamide PA6 and PA66 (UL94 V-0 at 25–30% loading)
  • Thermoplastic polyurethane (TPU) and polyester (PBT/PET) compounds
  • Epoxy resin laminates and printed circuit board prepregs
  • Polyolefin cable and wire compounds requiring halogen-free FR certification
  • Intumescent coatings as acid and gas source synergist with APP

Key Features

  • High thermal stability (>320 °C) compatible with engineering plastics processing temperatures
  • Synergistic N–P mechanism delivers both gas-phase dilution and condensed-phase char barrier
  • Halogen-free and low-smoke, compliant with IEC 60332, EN 45545, and UL94 V-0 standards
  • Low moisture absorption prevents processing issues and maintains long-term electrical properties

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Melamine Polyphosphate (MPP) chemical structure

CAS Number

218768-84-4

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