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Fluoroethylene Carbonate (FEC) SEI Additive

CAS Number: 114435-02-8

Fluoroethylene carbonate (FEC) is a high-performance film-forming electrolyte additive that dramatically improves cycle life and Coulombic efficiency of silicon and silicon-oxide anodes by forming a stable, fluorine-rich SEI layer. It is also widely used in lithium metal and NMC high-voltage electrolyte formulations.

Technical Specifications

appearanceColorless transparent liquid
purity (%)≥99.9
GC purity (%)≥99.9
acidity (ppm)≤10
moisture (ppm)≤20
density (g/mL, 25°C)1.452–1.456

Applications

  • Silicon/SiOx anode electrolyte additive (2–10 wt%)
  • Lithium metal battery SEI formation additive
  • High-voltage NMC electrolyte co-additive
  • Hard carbon sodium-ion battery electrolyte
  • All-solid-state lithium battery interface modifier

Key Features

  • Generates a thin, elastic, fluorine-rich SEI that accommodates silicon volumetric expansion
  • Reduces initial capacity loss and boosts first-cycle Coulombic efficiency on Si anodes
  • Suppresses electrolyte decomposition at high voltages (>4.3V)
  • Synergistic with VC and LiDFP additives for optimized electrolyte performance

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Fluoroethylene Carbonate (FEC) SEI Additive chemical structure

CAS Number

114435-02-8

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