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Hydroxypropyl Methacrylate

CAS Number: 27813-02-1

Hydroxypropyl methacrylate (HPMA) is a hydroxyl-functional methacrylic monomer that incorporates pendant hydroxyl groups with greater hydrophobicity than HEA. It is the preferred functional monomer for high-solids acrylic coatings, automotive refinish systems, and thermosetting powder coatings where controlled crosslink density and weather resistance are critical.

Technical Specifications

appearanceColorless to pale yellow transparent liquid
purity (%)≥96.0
water content (%)≤0.1
inhibitor (MEHQ, ppm)200 ± 50
hydroxyl value (mg KOH/g)390–410

Applications

  • High-solids and 2K automotive topcoat acrylic resins
  • Powder coating thermosetting acrylic resin synthesis
  • Automotive OEM and refinish clear coat formulations
  • Industrial maintenance coatings requiring UV stability
  • Coil and pre-coated metal coating systems

Key Features

  • Higher hydrophobicity than HEA yields better water resistance in crosslinked coatings
  • Alpha-methyl group increases copolymer hardness and chemical resistance
  • Precisely defined hydroxyl equivalent weight for stoichiometric NCO/OH formulation
  • Low yellowing tendency suitable for clearcoats and light-colored topcoats

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Hydroxypropyl Methacrylate chemical structure

CAS Number

27813-02-1

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