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Diphenyl Carbonate

CAS Number: 102-09-0

Diphenyl carbonate (DPC) is the non-phosgene carbonylating monomer for melt-process polycarbonate production. In the Asahi Kasei DPC process, DPC reacts with bisphenol A under melt transesterification to produce optical-quality PC resin without any phosgene or solvent. DPC is produced from dimethyl carbonate and phenol, enabling a fully phosgene-free PC supply chain.

Technical Specifications

appearanceWhite crystalline flakes or powder
purity (%)≥99.9
acidity (ppm)≤5
water content (%)≤0.05
melting point (°C)79–81

Applications

  • Melt polycarbonate (PC) production via BPA transesterification
  • Polycarbonate copolymers for specialty optical and film applications
  • Synthesis of polycarbonate-polysiloxane copolymers
  • Phosgene-free aliphatic polycarbonate diol synthesis
  • Pharmaceutical carbamate intermediate synthesis

Key Features

  • Phosgene-free route enables safer PC production facilities with simplified handling
  • Ultra-high purity minimizes color formation in optical-grade polycarbonate
  • Produces phenol as only by-product, which is recyclable back to DMC–DPC chain
  • Compatible with interfacial PC process as drop-in monomer substitute

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Diphenyl Carbonate chemical structure

CAS Number

102-09-0

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