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Zinc Borate (Firebrake ZB) Flame Retardant

CAS Number: 138265-88-0

Zinc borate (2ZnO·3B2O3·3.5H2O, Firebrake ZB) is a multifunctional inorganic flame retardant, smoke suppressant, and afterglow suppressant used in halogenated and halogen-free polymer systems. It functions through endothermic dehydration, boron oxide glass-forming char promotion, and zinc ion Lewis acid catalysis. Zinc borate is widely used as a partial replacement for antimony trioxide in halogen systems, and as a synergist with ATH or MDH in halogen-free cable compounds, providing additional smoke suppression benefits.

Technical Specifications

appearanceWhite powder
ZnO content (%)37–39
B2O3 content (%)47–49
dehydration onset (°C)290–300
particle size D50 (µm)5–8
water of crystallization (%)13–14

Applications

  • Partial Sb2O3 replacement (up to 50%) in PVC and halogenated polymer FR systems
  • Halogen-free cable and wire compounds as ATH/MDH synergist for improved smoke suppression
  • Intumescent fire-retardant coatings as afterglow suppressant and char stabilizer
  • Cellulosic and wood composite products requiring combined FR and mold resistance
  • Rubber conveyor belts and seals requiring FR with smoke suppression certification

Key Features

  • Triple functionality: flame retardancy, smoke suppression, and afterglow inhibition in a single mineral additive
  • Partial Sb2O3 replacement (up to 50%) reduces cost while maintaining halogen FR system performance
  • High dehydration onset (290–300 °C) stable during PVC and engineering plastic processing
  • Synergy with ATH/MDH in halogen-free systems provides additional LOI improvement and smoke reduction

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Zinc Borate (Firebrake ZB) Flame Retardant chemical structure

CAS Number

138265-88-0

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