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Tetrakis(hydroxymethyl)phosphonium Sulfate (THPS)

CAS Number: 124-64-1

Tetrakis(hydroxymethyl)phosphonium sulfate (THPS) is a reactive organophosphorus flame retardant and biocide widely used for durable flame retardant finishing of cotton and cotton-blend textiles. It forms a cross-linked three-dimensional phosphorus network within cellulose fiber upon curing, providing wash-durable flame retardancy that withstands 50+ industrial launderings. THPS-treated fabrics meet EN ISO 15025, EN 11611, and NFPA 701 standards required for protective workwear.

Technical Specifications

pH (neat)2.0–4.0
appearanceColorless to pale yellow liquid
water solubilityMiscible
phosphorus content (%)11–12
active THPS content (%)75–80
specific gravity (20°C)1.35–1.40

Applications

  • Durable flame-retardant finishing of cotton workwear and protective clothing
  • Military and defense FR fabric treatment meeting NATO and MIL-SPEC requirements
  • Industrial fire-retardant uniforms for oil and gas, electrical, and chemical industries
  • Cotton theatrical and stage curtain FR treatment
  • Biocidal treatment of oilfield injection water as secondary application

Key Features

  • Reactive cross-linking mechanism provides wash-durable FR performance surviving 50+ industrial laundry cycles
  • Low add-on levels (15–20% on fabric weight) with minimal handle change versus untreated fabric
  • Meets EN ISO 15025 and EN 11611 standards for protective workwear in high-risk industries
  • Dual-function product: FR finishing and biocidal activity in oilfield water treatment applications

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Tetrakis(hydroxymethyl)phosphonium Sulfate (THPS) chemical structure

CAS Number

124-64-1

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