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Benzoyl Peroxide

CAS Number: 94-36-0

Benzoyl peroxide (BPO) is a thermally labile organic peroxide initiator that generates phenyl and benzoyloxy radicals upon decomposition between 70–100°C. It is the most common initiator for suspension polymerization, free-radical crosslinking of unsaturated polyester and vinyl ester resins, and vulcanization of silicone rubbers. Available in powder (75–78% active) and paste grades.

Technical Specifications

appearanceWhite granular powder or paste
moisture (%)22–25 (wetted grade)
purity (as BPO, %)75–78 (phlegmatized grade)
particle size (mesh)90% through 40 mesh
active oxygen content (%)6.5–7.1

Applications

  • Suspension polymerization of polystyrene and EPS beads
  • Free-radical cure of unsaturated polyester and vinyl ester resins
  • Hot-press vulcanization of silicone rubber compounds
  • PMMA dental and bone cement curing agent
  • Acne treatment and pharmaceutical API synthesis

Key Features

  • Generates highly reactive phenyl radicals for fast cure of polyester and vinyl ester resins
  • Phlegmatized grade reduces deflagration risk for safer handling and transport
  • Broad compatibility with promoters (cobalt, DMPT) for room-temperature cure
  • Established regulatory status for pharmaceutical and food-contact applications

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Benzoyl Peroxide chemical structure

CAS Number

94-36-0

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