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Tris(trimethylsilyl) Phosphate (TTSP) Electrolyte Additive

CAS Number: 10497-05-9

TTSP is a silicon-containing multifunctional electrolyte additive that scavenges trace HF generated from LiPF6 hydrolysis, forms a protective CEI on NMC cathodes, and improves cycle stability at elevated temperatures. Used at 0.5–2 wt%, it is particularly effective in high-voltage (>4.3V) NMC811 and NCA systems.

Technical Specifications

appearanceColorless to pale yellow liquid
purity (%)≥99.0
acidity (ppm)≤30
Si content (%)≥23.0
moisture (ppm)≤50

Applications

  • HF scavenger in LiPF6-based electrolytes
  • NMC/NCA cathode CEI-forming additive
  • High-voltage (>4.3V) electrolyte stabilizer
  • High-temperature cycle life improvement additive
  • Multi-additive electrolyte formulation component

Key Features

  • Reacts rapidly with HF to form trimethylsilyl fluoride (TMSF), protecting battery components
  • Deposits a thin CEI layer on Ni-rich cathodes, suppressing irreversible oxygen release
  • Improves capacity retention at 45°C+ cycling conditions in high-nickel cells
  • Compatible with FEC, LiDFP, and VC for comprehensive multi-additive strategies

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Tris(trimethylsilyl) Phosphate (TTSP) Electrolyte Additive chemical structure

CAS Number

10497-05-9

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