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DOPO (9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide)

CAS Number: 35455-29-9

DOPO is a reactive organophosphorus flame retardant widely used as a building block for halogen-free fire-retardant polymers and epoxy systems. Its P–H active group allows covalent bonding into epoxy resins, polyesters, and polyurethanes, providing durable flame retardancy without migration or leaching. DOPO-based systems meet stringent UL 94 V-0 ratings in printed circuit boards and electronic encapsulants.

Technical Specifications

appearanceWhite crystalline powder
purity (%)≥99
melting point (°C)115–118
acid value (mgKOH/g)≤1
phosphorus content (%)14.3

Applications

  • Halogen-free flame retardant epoxy resins for PCB laminates
  • Reactive flame retardant additive for polyurethane foams and elastomers
  • Phosphorus-containing polyester and nylon engineering plastics
  • Encapsulants and potting compounds for electronic components
  • Synthesis intermediate for DOPO-HQ and other advanced FR derivatives

Key Features

  • Reactive P–H group enables covalent integration into polymer backbones for non-migratory flame retardancy
  • Halogen-free phosphorus-based mechanism reduces toxic gas emission during combustion
  • High thermal stability up to 260°C suitable for high-performance electronics processing
  • Versatile building block compatible with epoxy, polyester, polyurethane, and nylon systems

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DOPO (9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) chemical structure

CAS Number

35455-29-9

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