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Carbon Tetrafluoride Plasma Etch Gas (CF4)

CAS Number: 75-73-0

Carbon tetrafluoride (CF4) is a versatile plasma etch gas used for etching silicon oxide, silicon nitride, and silicon in dry etch processes. When combined with oxygen, it etches SiO2 with high selectivity; alone or with H2, it is used for anisotropic silicon and nitride etch. CF4 also serves as a chamber cleaning gas and is used in remote plasma cleans for CVD reactors.

Technical Specifications

oxygen≤2 ppm
moisture≤1 ppm
nitrogen≤5 ppm
appearanceColorless odorless gas
purity (%)≥99.999 (5N semiconductor grade)

Applications

  • SiO2 and Si3N4 plasma etch (with O2 or H2)
  • Silicon plasma etch and surface clean
  • CVD chamber remote plasma clean
  • Contact and via oxide etch in CMOS
  • Compound semiconductor (GaAs, InP) dry etch

Key Features

  • Versatile etch chemistry compatible with oxide, nitride, and silicon processes
  • Tunable selectivity via addition of O2 (more oxide-selective) or H2 (more nitride-selective)
  • Lower GWP than SF6 for certain low-etch-rate applications
  • Non-flammable and non-toxic; easier to handle than fluorine-based etchants

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Carbon Tetrafluoride Plasma Etch Gas (CF4) chemical structure

CAS Number

75-73-0

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